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Seveneves - Neal Stephenson. On space exploration incentivized by an earth-wide catastrophic event.

The Culture Series - Ian Banks. Especially: The Player of Games. A series of space operas about the lives of technologically advanced civilizations.

The Last Question - Isaac Asimov. On solving entropy.

Blue Mars, Red Mars, Green Mars - Kim Stanely Robinson. A series of books on civilizational problems on the path to colonizing Mars.

Explore the Cosmos in 10 Classical Space Operas - Alan Brown. A link list of space operas.

The Moon is a Harsh Mistress - Robert. A. Heinlein. On political struggles on planetary colonies. 

The Dispossessed: An Ambiguous Utopia - Ursula K. LeGuin. On choosing amongst anarchism and other political regimes that govern different planets.

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